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D. (1970). Viscoelastic properties of polymers, John Wiley, New York. 28. Andrews, E. H. (1968). Fracture in polymers, Oliver and Boyd, London. 29. Andrews, E. H. (1974). 1. Mater. , 9, 887. 30. Bowden, P. B. (1973). In: The physics of glassy polymers, Ed. by R. N. , London, p. 279. 31. Yamini, S. & Young, R. J. (1980). 1. Mater. , 15, 1814. 32. Bowden, P. B. & Young, R. J. (1974). 1. Mater. , 9, 2034. 33. Bowden, P. B. & Raha, S. (1974). Phil. , 29, 149. 34. Argon, A. (1977). Phil. , 35, 917. 35.
Unlike an elastic material the strain lags somewhat behind the stress and so the variation of stress and strain 27 INTRODUCTION Stress system Strain system ar t ~--------------------~> d (J Fig. 11. Schematic representation of the variation of stress and strain with time indicating the input (1) and responses (R) for different types of loading. (a) Creep; (b) relaxation; (c) constant stress-rate; and (d) constant strain-rate. The dashed lines are for elastic materials and the solid lines for viscoelastic ones (after Williams 21 ).
12) where Cijkl is a fourth-rank tensor containing all the stiffness constants. In principle there are 9 x 9 = 81 stiffness constants but the number is considerably reduced using symmetry considerations and for an elastically isotropic solid such as a glassy polymer there are only two independent elastic constants.! Three elastic constants are normally used to describe the elastic behaviour of an isotropic solid-they are the Young's modulus, E, the shear modulus, CfJ, and the Poisson's ratio, v, only two of which are independent of each other.